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通过将 Eu2O3 和有机配体溶解在特定任务离子液体中获得的具有强发光性能的软材料。

Soft material with intense photoluminescence obtained by dissolving Eu2O3 and organic ligand into a task-specific ionic liquid.

作者信息

Li Huanrong, Shao Huifang, Wang Yige, Qin Dashan, Liu Binyuan, Zhang Wenjun, Yan Weidong

机构信息

School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China.

出版信息

Chem Commun (Camb). 2008 Nov 7(41):5209-11. doi: 10.1039/b810631b. Epub 2008 Sep 10.

DOI:10.1039/b810631b
PMID:18956071
Abstract

A task-specific ionic liquid containing a carboxylate group with the ability to dissolve metal oxide and organic ligands has been used as the solvent to prepare lanthanide complexes without the addition of extra solvent; thus a soft material with intense photoluminescence has been obtained by directly dissolving Eu(2)O(3), 2-thenoyltrifluoroacetone (TTA) and 1,10-phenanthroline (Phen) into the task-specific ionic liquid.

摘要

一种含有羧基、能够溶解金属氧化物和有机配体的特定任务离子液体已被用作溶剂,用于在不添加额外溶剂的情况下制备镧系元素配合物;因此,通过将Eu(2)O(3)、2-噻吩甲酰三氟丙酮(TTA)和1,10-菲咯啉(Phen)直接溶解在特定任务离子液体中,获得了一种具有强烈光致发光的软材料。

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