Li Huanrong, Shao Huifang, Wang Yige, Qin Dashan, Liu Binyuan, Zhang Wenjun, Yan Weidong
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China.
Chem Commun (Camb). 2008 Nov 7(41):5209-11. doi: 10.1039/b810631b. Epub 2008 Sep 10.
A task-specific ionic liquid containing a carboxylate group with the ability to dissolve metal oxide and organic ligands has been used as the solvent to prepare lanthanide complexes without the addition of extra solvent; thus a soft material with intense photoluminescence has been obtained by directly dissolving Eu(2)O(3), 2-thenoyltrifluoroacetone (TTA) and 1,10-phenanthroline (Phen) into the task-specific ionic liquid.
一种含有羧基、能够溶解金属氧化物和有机配体的特定任务离子液体已被用作溶剂,用于在不添加额外溶剂的情况下制备镧系元素配合物;因此,通过将Eu(2)O(3)、2-噻吩甲酰三氟丙酮(TTA)和1,10-菲咯啉(Phen)直接溶解在特定任务离子液体中,获得了一种具有强烈光致发光的软材料。