Muzzarelli R A, Sipos L
G. Ciamician Chemical Institute, University of Bologna, Via Selmi 2, Bologna 40126, Italy.
Talanta. 1971 Sep;18(9):853-8. doi: 10.1016/0039-9140(71)80141-8.
Anodic stripping voltammetry with a composite graphite-mercury electrode was applied in order to demonstrate that chitosan can collect naturally occurring zinc, cadmium, lead and copper from sea-water, with high yields. Chitosan columns (15 x 10mm) can be used to preconcentrate trace metals from 3 1. of sea-water; the four elements can be selectively eluted with electrolytes suitable for conventional polarographic determinations. The method can find application in sea-water pollution survey and detection.
采用复合石墨汞电极的阳极溶出伏安法,以证明壳聚糖能够从海水中高效收集天然存在的锌、镉、铅和铜。壳聚糖柱(15×10毫米)可用于对3升海水中的痕量金属进行预富集;这四种元素可用适合传统极谱测定的电解质进行选择性洗脱。该方法可应用于海水污染调查与检测。