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用N-间甲苯基-N-苯基羟胺萃取分光光度法测定钒及其在煤和粉煤灰中的应用

Extraction-spectrophotometric determination of vanadium with N-m-tolyl-N-phenylhydroxylamine and its application to coal and coal fly-ash.

作者信息

Inoue S, Hoshi S, Matsubara M

机构信息

Department of Environmental Engineering, Kitami Institute of Technology, Kitami-shi, 090 Japan.

出版信息

Talanta. 1986 Jul;33(7):611-3. doi: 10.1016/0039-9140(86)80139-4.

DOI:10.1016/0039-9140(86)80139-4
PMID:18964150
Abstract

N-m-Tolyl-N-phenylhydroxylamine is proposed for the spectrophotometric determination of small amounts of vanadium. The reddish-violet complex formed with the reagent in 3-6M hydrochloric acid after extraction with chloroform shows an absorption maximum at 530 nm, and obeys Beer's law for 0-76.5 mug of vanadium in 10 ml of chloroform. The proposed method has been successfully applied to the determination of vanadium in coal and coal fly-ash.

摘要

有人提出用N-间甲苯基-N-苯基羟胺分光光度法测定少量钒。该试剂在3-6M盐酸中与钒形成的红紫色络合物,用氯仿萃取后,在530nm处有最大吸收,在10ml氯仿中,0-76.5μg钒符合比尔定律。该方法已成功应用于煤和粉煤灰中钒的测定。

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