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用聚氨酯泡沫吸附剂分离碲和硒

The separation of tellurium and selenium by polyurethane foam sorbents.

作者信息

Stewart I I, Chow A

机构信息

Department of Chemistry, University of Manitoba, Winnipeg, MB, Canada.

出版信息

Talanta. 1993 Sep;40(9):1345-52. doi: 10.1016/0039-9140(93)80208-9.

DOI:10.1016/0039-9140(93)80208-9
PMID:18965788
Abstract

Tellurium and selenium can be sorbed from hydrochloric acid and hydrobromic acid solution by both polyether and polyester-based polyurethane foam. Although some acid is needed, the substitution of sodium chloride or sodium bromide increases the extraction significantly. Tellurium is extracted rapidly with > 99% sorbed in 2 min from 1.0/5.0M and 2.0/4.0M hydrochloric acid/sodium bromide. Selenium can also be sorbed quantitatively but much more slowly so that a separation is possible based on the relative rates of extraction. The capacity of polyether foam is 3% by weight of tellurium.

摘要

聚醚型和聚酯型聚氨酯泡沫均可从盐酸和氢溴酸溶液中吸附碲和硒。虽然需要一些酸,但用氯化钠或溴化钠替代会显著提高萃取率。碲能被快速萃取,在2分钟内,从1.0/5.0M和2.0/4.0M盐酸/溴化钠溶液中吸附率大于99%。硒也能被定量吸附,但速度要慢得多,因此基于相对萃取速率可实现分离。聚醚泡沫对碲的吸附容量为3%(重量)。

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