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镁选择性试纸条。

Magnesium-selective test strip.

作者信息

Capitán-Vallvey L F, Ramos M D Fernández, Gálvez P Alvarez de Cienfuegos, Gómez J

机构信息

Department of Analytical Chemistry, Faculty of Sciences, University of Granada, Avda. Fuentenueva s/n, Granada 18071, Spain.

出版信息

Talanta. 2005 Jan 15;65(1):239-45. doi: 10.1016/j.talanta.2004.06.017.

Abstract

A selective test strip based on an ion-exchange mechanism to determine magnesium is described. This optical and reversible test strip, made on a transparent polyester sheet, has a circular polymeric film of plasticised PVC that contains all of the reagents necessary to produce a response to magnesium, namely, a cation-selective neutral ionophore, 2-amino-N,N'-diheptyl-N,N'-dimethyl-butanediamide, a chromoionophore, N,N-diethyl-5-(octadecanoylimino)-5H-benzo[a]phenoxazine-9-amine, and potassium tetrakis (4-chlorophenyl)borate (TCPB) as a lipophilic salt, which is evaluated by absorbance measurement at 655nm in a standard photometer. The experimental variables that influence test strip response, especially in terms of selectivity and response time, have been studied. The test strip responded linearly to magnesium between 0.009 and 160mM in activities. The reproducibility intermembrane at a medium level of the range was 8.0%, as R.S.D., of [Formula: see text] , and 5.9% as R.S.D. intramembrane. The procedure was applied to the determination of magnesium in different types of waters (tap, well and mineral) validating the results against a reference procedure. This proposed method is quick, inexpensive, selective and sensitive and uses only conventional instrumentation.

摘要

本文描述了一种基于离子交换机制测定镁的选择性测试条。这种光学可逆测试条制作在透明聚酯片上,有一个由增塑聚氯乙烯制成的圆形聚合物膜,其中包含产生对镁响应所需的所有试剂,即阳离子选择性中性离子载体2-氨基-N,N'-二庚基-N,N'-二甲基丁二酰胺、发色离子载体N,N-二乙基-5-(十八烷酰亚氨基)-5H-苯并[a]吩恶嗪-9-胺,以及作为亲脂性盐的四(4-氯苯基)硼酸钾(TCPB),通过在标准光度计中655nm处的吸光度测量进行评估。研究了影响测试条响应的实验变量,特别是选择性和响应时间方面。测试条对镁的活性在0.009至160mM之间呈线性响应。在该范围的中等水平下,膜间的重现性以相对标准偏差(R.S.D.)计为8.0%,膜内为5.9%。该方法应用于不同类型水(自来水、井水和矿泉水)中镁的测定,并与参考方法验证结果。该方法快速、廉价、具有选择性且灵敏,仅使用常规仪器。

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