由二硫代草酰胺铜配合物组成的高度取向的结晶表面配位聚合物的构建。
Construction of highly oriented crystalline surface coordination polymers composed of copper dithiooxamide complexes.
作者信息
Kanaizuka Katsuhiko, Haruki Rie, Sakata Osami, Yoshimoto Mamoru, Akita Yasuyuki, Kitagawa Hiroshi
机构信息
Department of Chemistry, Faculty of Science, Kyushu University, Fukuoka, Japan.
出版信息
J Am Chem Soc. 2008 Nov 26;130(47):15778-9. doi: 10.1021/ja806799t.
PMID:18983147
Abstract
Layer-by-layer bottom-up crystal engineering of metal-organic crystals at the surface of sapphire or glass from organic (rubeanic acid and derivatives) and inorganic (Cu(2+)) components which when mixed in solution form instantly an amorphous solid with high proton conduction.
摘要
通过自下而上的逐层晶体工程，在蓝宝石或玻璃表面由有机成分（硫氰酸及其衍生物）和无机成分（Cu(2+)）构建金属有机晶体，这些成分在溶液中混合时会立即形成具有高质子传导性的无定形固体。
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