用于过氧化氢温和氧化硫化合物的介孔二氧化硅 - 二氧化钛催化剂的非水解合成
Non-hydrolytic synthesis of mesoporous silica-titania catalysts for the mild oxidation of sulfur compounds with hydrogen peroxide.
作者信息
Cojocariu Ana Mihaela, Mutin P Hubert, Dumitriu Emil, Fajula François, Vioux André, Hulea Vasile
机构信息
Institut Charles Gerhardt, UMR 5253, CNRS-UM2-ENSCM-UM1, Université Montpellier 2, Place Eugène Bataillon, Montpellier Cedex 5, France.
出版信息
Chem Commun (Camb). 2008 Nov 14(42):5357-9. doi: 10.1039/b811668g. Epub 2008 Sep 18.
DOI:10.1039/b811668g
PMID:18985209
Abstract
A SiO(2)-TiO(2) mesoporous xerogel prepared in one-step by a non-hydrolytic route shows excellent performance in the mild oxidation of sulfides, sulfoxides and thiophenes with aqueous solutions of H(2)O(2).
摘要
通过非水解路线一步制备的SiO(2)-TiO(2)介孔干凝胶在使用H(2)O(2)水溶液对硫化物、亚砜和噻吩进行温和氧化时表现出优异的性能。
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