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七个同构的一维Ln3+配合物Ln(BTA)(HCOO)(H2O)3（H2BTA = 双（四唑基）胺，Ln = Pr、Gd、Eu、Tb、Dy、Er、Yb）以及两个三维Ln3+配合物Ln(HCOO)3（Ln = Pr、Nd）的合成、结构与性质

Syntheses, structures and properties of seven isomorphous 1D Ln3+complexes Ln(BTA)(HCOO)(H2O)3 (H2BTA = bis(tetrazoly)amine, Ln = Pr, Gd, Eu, Tb, Dy, Er, Yb) and two 3D Ln3+ complexes Ln(HCOO)3 (Ln = Pr, Nd).

作者信息

Lin Jiao-Min, Guan Yang-Fan, Wang Dong-Yao, Dong Wen, Wang Xiu-Teng, Gao Song

机构信息

Department of Chemistry, Guangzhou University, Guangzhou, 510006, P. R. China.

出版信息

Dalton Trans. 2008 Nov 28(44):6165-9. doi: 10.1039/b808394k. Epub 2008 Oct 6.

DOI:10.1039/b808394k
PMID:18985249
Abstract

Seven isomorphous 1D chain Ln3+ complexes Ln(BTA)(HCOO)(H2O)3 (Ln = Pr (1), Gd (2), Eu (3), Tb (4) Dy (5), Er (6) and Yb (7)), and two formate coordinating and bridging 3D Ln3+ complexes Ln(HCOO)3 (Ln = Pr (8) and Nd (9)) have been synthesized and characterized by single crystal X-ray diffraction analysis. Although the Ln3+ ions in 1-7 have different radius, the trivalent lanthanide ions in 1-7 show the same coordinated environment. The well-defined single crystal structures of 8 and 9 are first samples for formate-bridged Ln3+ metallic complexes. The luminescent properties of solid samples of 2-5 at room temperature and the magnetic property of 2 have been also reported and discussed in this paper.

摘要

已合成了七个同构的一维链状Ln3+配合物Ln(BTA)(HCOO)(H2O)3（Ln = Pr (1)、Gd (2)、Eu (3)、Tb (4)、Dy (5)、Er (6) 和Yb (7)），以及两个甲酸根配位和桥连的三维Ln3+配合物Ln(HCOO)3（Ln = Pr (8) 和Nd (9)），并通过单晶X射线衍射分析对其进行了表征。尽管1-7中的Ln3+离子半径不同，但1-7中的三价镧系离子显示出相同的配位环境。8和9明确的单晶结构是甲酸根桥连Ln3+金属配合物的首个实例。本文还报道并讨论了2-5固体样品在室温下的发光性质以及2的磁性。

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