Yuan Liyong, Peng Jing, Xu Ling, Zhai Maolin, Li Jiuqiang, Wei Genshuan
Beijing National Laboratory for Molecular Sciences (BNLMS), Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, PR China.
Dalton Trans. 2008 Dec 7(45):6358-60. doi: 10.1039/b811413g. Epub 2008 Sep 24.
The preliminary results presented here show that gamma-irradiation of ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) markedly decreases Sr2+ partitioning in the crown ether/[C4mim][PF6] extraction phase due to the competition between radiation-generated H+ and Sr2+ to interact with the crown ether, however, washing irradiated [C4mim][PF6] with water gives a simple way of recycling the ionic liquid.
此处展示的初步结果表明，对离子液体1-丁基-3-甲基咪唑鎓六氟磷酸盐（[C4mim][PF6]）进行γ辐照，会显著降低冠醚/[C4mim][PF6]萃取相中Sr2+的分配，这是由于辐射产生的H+与Sr2+之间存在与冠醚相互作用的竞争；然而，用水洗涤辐照后的[C4mim][PF6]提供了一种回收该离子液体的简单方法。
