Breaking the 1.80 A barrier of the Cr-Cr multiple bond between Cr(II) atoms.

作者信息

Horvath Steven, Gorelsky Serge I, Gambarotta Sandro, Korobkov Ilia

机构信息

Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa ON K1N 6N5, Canada.

出版信息

Angew Chem Int Ed Engl. 2008;47(51):9937-40. doi: 10.1002/anie.200804048.

DOI:10.1002/anie.200804048

PMID:19003840

Abstract

摘要

相似文献

Breaking the 1.80 A barrier of the Cr-Cr multiple bond between Cr(II) atoms.

Angew Chem Int Ed Engl. 2008;47(51):9937-40. doi: 10.1002/anie.200804048.

Bond length and bond order in one of the shortest Cr-Cr bonds.最短的铬-铬键之一的键长和键级。

Inorg Chem. 2008 Dec 15;47(24):11455-7. doi: 10.1021/ic801537w.

Bonding nature of open-lantern-type dinuclear Cr(II) complexes. Theoretical study with the MRMP2 method.开灯笼型双核Cr(II)配合物的键合性质。采用MRMP2方法的理论研究。

J Phys Chem A. 2009 Apr 2;113(13):3202-9. doi: 10.1021/jp809597m.

Peculiarities of multiple Cr-Cr bonding. Insights from the analysis of domain-averaged Fermi holes.多重Cr-Cr键的特性。基于域平均费米空穴分析的见解。

J Phys Chem A. 2009 Jul 23;113(29):8394-400. doi: 10.1021/jp903144q.

Metal-olefin bond energies in M(CO)5(C2H(4-n)Cln) M = Cr, Mo, W; n = 0-4: electron-withdrawing olefins do not increase the bond strength.M(CO)5(C2H(4-n)Cln) 中金属 - 烯烃键能（M = Cr、Mo、W；n = 0 - 4）：吸电子烯烃不会增加键强度。

J Phys Chem A. 2009 Sep 3;113(35):9692-9. doi: 10.1021/jp9027468.

Self-assembly of luminescent alkynyl-based platinum-cadmium complexes containing auxiliary diimine or terpyridine ligands.含有辅助二亚胺或三联吡啶配体的发光炔基铂 - 镉配合物的自组装。

Inorg Chem. 2009 Jun 15;48(12):5250-62. doi: 10.1021/ic9002109.

Cr(CO)3-activated Diels-Alder reaction on single-wall carbon nanotubes: a DFT investigation.单壁碳纳米管上Cr(CO)₃活化的狄尔斯-阿尔德反应：一项密度泛函理论研究

Chemistry. 2009;15(16):4182-9. doi: 10.1002/chem.200802440.

Why the chromyl bond is stronger than the perchromyl bond in high-valent oxochromium(IV,V) complexes of tris(pentafluorophenyl)corrole.在三（五氟苯基）卟啉的高价氧铬（IV，V）配合物中，为什么铬酰键比过铬酰键更强。

J Am Chem Soc. 2009 Oct 14;131(40):14214-5. doi: 10.1021/ja906393r.

O-H...O versus O-H...S hydrogen bonding I: Experimental and computational studies on the p-cresol x H2O and p-cresol x H2S complexes.O-H...O与O-H...S氢键I：对甲酚xH₂O和对甲酚xH₂S配合物的实验与计算研究

J Phys Chem A. 2009 May 14;113(19):5633-43. doi: 10.1021/jp9009355.

Experimental and theoretical investigation of simple terminal group 6 arsenide As[triple bond]MF3 molecules.简单端基6族砷化物As≡MF₃分子的实验与理论研究

J Phys Chem A. 2009 May 28;113(21):6064-9. doi: 10.1021/jp901308n.

引用本文的文献

A non-metal-to-metal I-Ag coordination bond.一种非金属到金属的I-Ag配位键。

Nat Commun. 2025 Aug 13;16(1):7532. doi: 10.1038/s41467-025-62191-1.

Carboalumination of a chromium–chromium quintuple bond.碳化铬-铬五重键的碳化作用。

Nat Chem. 2009 Jul;1(4):322-5. doi: 10.1038/nchem.255.

Ultrashort metal-metal distances and extreme bond orders.超短金属-金属距离和极端键级。

Nat Chem. 2009 Oct;1(7):529-36. doi: 10.1038/nchem.359. Epub 2009 Sep 23.

Nature of bonding in complexes containing "supershort" metal-metal bonds. raman and theoretical study of M2(dmp)4 [M = Cr (natural abundance Cr, 50Cr, and 54Cr) and Mo; dmp = 2,6-dimethoxyphenyl].含“超短”金属-金属键配合物的成键本质。M2(dmp)4 [M = Cr（天然丰度 Cr、50Cr 和 54Cr）和 Mo；dmp = 2,6-二甲氧基苯基]的拉曼和理论研究。

J Am Chem Soc. 2010 Feb 17;132(6):1839-47. doi: 10.1021/ja9055504.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验