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白花越桔对铅(II)离子的生物吸附特性研究:批次和动态流动研究

Investigation of the biosorption characteristics of lead(II) ions onto Symphoricarpus albus: Batch and dynamic flow studies.

作者信息

Akar Sibel Tunali, Gorgulu Asli, Anilan Burcu, Kaynak Zerrin, Akar Tamer

机构信息

Department of Chemistry, Faculty of Arts and Science, Eskişehir Osmangazi University, Eskişehir, Turkey.

出版信息

J Hazard Mater. 2009 Jun 15;165(1-3):126-33. doi: 10.1016/j.jhazmat.2008.09.089. Epub 2008 Sep 30.

Abstract

This work reports the results of the study for lead(II) binding by the natural and low cost biosorbent Symphoricarpus albus. Batch biosorption experiments demonstrated the high rate of lead(II) biosorption and the kinetic data were successfully described by a pseudo-second-order model. Biosorption of lead(II) onto S. albus biomass showed a pH-dependent profile and lead(II) biosorption was higher when pH or temperature was increased. As much as 88.5% removal of lead(II) is also possible in the multi-metal mixture. The Langmuir isotherm better fits the biosorption data and the monolayer biosorption capacity was 3.00 x 10(-4) mol g(-1) at 45 C. The biomass was characterized with FTIR and SEM analysis. Desorption studies revealed that the natural biomass could be regenerated using 10mM HNO(3) solution with about 99% recovery and reused in five biosorption-desorption cycles. Therefore, S. albus which is cheap, highly selective and easily regenerable seems to be a promising substrate to entrap lead(II) ions in aqueous solutions.

摘要

本研究报告了天然低成本生物吸附剂白毛补血草对铅(II)的吸附研究结果。批量生物吸附实验表明铅(II)的生物吸附速率很高,动力学数据成功地用准二级模型进行了描述。铅(II)在白毛补血草生物质上的吸附呈现出pH依赖性,当pH值或温度升高时,铅(II)的生物吸附量更高。在多金属混合物中,铅(II)的去除率也可达88.5%。Langmuir等温线更适合生物吸附数据,在45℃时单层生物吸附容量为3.00×10(-4)mol g(-1)。通过傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)分析对生物质进行了表征。解吸研究表明,天然生物质可用10mM硝酸溶液再生,回收率约为99%,并可在五个生物吸附-解吸循环中重复使用。因此,廉价、高选择性且易于再生的白毛补血草似乎是捕获水溶液中铅(II)离子的有前景的基质。

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