Oh Jeong-Wook, Lee Yeon Ok, Kim Tae Hyun, Ko Kyoung Chul, Lee Jin Yong, Kim Hasuck, Kim Jong Seung
School of Chemistry, Seoul National University, Seoul 151-747, Republic of Korea.
Angew Chem Int Ed Engl. 2009;48(14):2522-4. doi: 10.1002/anie.200804669.
A very generous donor: The electrochemiluminescence (ECL) efficiency and radical stability of pyrene, a poor ECL luminophore, are markedly improved as the number of peripheral multidonor units increased in a series of compounds (see picture). Photophysical and electrochemical studies and theoretical calculations have contributed to the understanding of the ECL enhancement, which is a step forward in the development of new light-emitting materials.
芘是一种较差的电化学发光(ECL)发光体,在一系列化合物中,随着外围多供体单元数量的增加,芘的ECL效率和自由基稳定性显著提高(见图)。光物理和电化学研究以及理论计算有助于理解ECL增强现象,这是新型发光材料开发中的一大进步。