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通过炔基芘衍生物上的外围多供体增强电致化学发光和自由基稳定性。

Enhancement of electrogenerated chemiluminescence and radical stability by peripheral multidonors on alkynylpyrene derivatives.

作者信息

Oh Jeong-Wook, Lee Yeon Ok, Kim Tae Hyun, Ko Kyoung Chul, Lee Jin Yong, Kim Hasuck, Kim Jong Seung

机构信息

School of Chemistry, Seoul National University, Seoul 151-747, Republic of Korea.

出版信息

Angew Chem Int Ed Engl. 2009;48(14):2522-4. doi: 10.1002/anie.200804669.

DOI:10.1002/anie.200804669
PMID:19040242
Abstract

A very generous donor: The electrochemiluminescence (ECL) efficiency and radical stability of pyrene, a poor ECL luminophore, are markedly improved as the number of peripheral multidonor units increased in a series of compounds (see picture). Photophysical and electrochemical studies and theoretical calculations have contributed to the understanding of the ECL enhancement, which is a step forward in the development of new light-emitting materials.

摘要

一位非常慷慨的捐赠者

芘是一种较差的电化学发光(ECL)发光体,在一系列化合物中,随着外围多供体单元数量的增加,芘的ECL效率和自由基稳定性显著提高(见图)。光物理和电化学研究以及理论计算有助于理解ECL增强现象,这是新型发光材料开发中的一大进步。

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