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新型三维3d - 4f微孔磁体表现出选择性气体吸附行为。

Novel three-dimensional 3d-4f microporous magnets exhibiting selective gas adsorption behavior.

作者信息

Li Cui-Jin, Lin Zhuo-Jia, Peng Meng-Xia, Leng Ji-Dong, Yang Ming-Mei, Tong Ming-Liang

机构信息

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, PR China.

出版信息

Chem Commun (Camb). 2008 Dec 21(47):6348-50. doi: 10.1039/b815024a. Epub 2008 Oct 29.

DOI:10.1039/b815024a
PMID:19048151
Abstract

Three microporous Ln-Co-pyta heterometallic compounds [Ln4Co3(pyta)6(H2O)9].5H2O (Ln = Sm (1), Eu (2), Gd (3); H3pyta = 2,4,6-pyridinetricarboxylic acid) have interesting selective adsorption abilities towards H2/N2 and CO2/N2 because of size-selective effects; magnetic analysis reveals that has a ferromagnetic behavior.

摘要

三种微孔镧系-钴-吡啶三甲酸异金属化合物[Ln4Co3(pyta)6(H2O)9].5H2O（Ln = Sm (1)、Eu (2)、Gd (3)；H3pyta = 2,4,6-吡啶三甲酸）由于尺寸选择效应，对H2/N2和CO2/N2具有有趣的选择性吸附能力；磁性分析表明其具有铁磁行为。

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