Yu Yinni, Blake Phillip, Roper D Keith
Department of Chemical Engineering, 3290 MEB, University of Utah, Salt Lake City, Utah 84112, USA.
Langmuir. 2009 Jan 6;25(1):59-63. doi: 10.1021/la801953z.
Combining a modified two-step chemical etch method with equations to predict etch parameters and photon-plasmon phase-matching resulted in single-mode tapered optical fibers (TOFs) to optimize electromagnetic field enhancement. The phase-matching equation was used to identify the angle of incidence near the TOF cutoff radius at which surface plasmon resonance (SPR) is maximized. The axisymmetric Young-Laplace equation was used to predict the angle of incidence from the fabrication of a TOF via chemical etching. An optimal cone angle of 20.0 degrees , angles of incidence averaging (81.6 +/- 1.9) degrees , and tip diameters of (80.0 +/- 14.1) nm were achieved through a two-step etching process. These TOF characteristics maximize SPR excitation and field enhancement. The refractive index for optimized SPR excitation in the fabricated TOFs at a wavelength of 650 nm was found to be 1.343.
将改进的两步化学蚀刻方法与用于预测蚀刻参数和光子 - 等离子体相位匹配的方程式相结合,得到了单模锥形光纤(TOF),以优化电磁场增强。相位匹配方程用于确定在TOF截止半径附近使表面等离子体共振(SPR)最大化的入射角。轴对称的杨 - 拉普拉斯方程用于通过化学蚀刻制造TOF来预测入射角。通过两步蚀刻工艺实现了20.0度的最佳锥角、平均入射角为(81.6±1.9)度以及(80.0±14.1)纳米的尖端直径。这些TOF特性使SPR激发和场增强最大化。发现在制造的TOF中,在650纳米波长下优化SPR激发的折射率为1.343。