Ou Dong-ni, Liu Min, Xu Shi-yuan, Cheng Shu-bo, Hou Li-jun, Gao Lei
Key Laboratory of Geographic Information Science of the Ministry of Education, School of Resources and Environment Science, East China Normal University, Shanghai 200062, China.
Huan Jing Ke Xue. 2008 Sep;29(9):2392-8.
Parent PAHs have been quantified in suspended particulate matters from the Yangtze Estuarine and Coastal Areas. The results show that the concentrations of total PAHs ranged from 2278.79-14293.98 ng/g, and were characterized by greatest content near sewage discharge point with trend to decrease by increasing distance. As for PAHs composition, 4-6 rings PAHs were dominant while 2-3 rings PAHs were relative low. Cluster analysis found that except urban sewage discharge, the hydrodynamic force was influencing PAHs distribution patterns. Moreover, the content of suspended particulate matters, organic carbon and soot carbon of suspended particulate matters also play the important roles in PAHs distribution from the Yangtze estuarine and nearby coastal areas. Principal component analysis and PAH ratios demonstrated that uncompleted combustion of fossil fuels was the main source of PAHs in coastal areas, as well as a few anthropogenic releases of oil and oil products. Ecological risk assessment indicated that most of PAH compounds exceeded the effects range ER-L values and ISQV-L values, which might certain potential damage to the Yangtze Estuary ecosystem.
已对长江河口和沿海地区悬浮颗粒物中的母体多环芳烃进行了定量分析。结果表明,总多环芳烃浓度范围为2278.79 - 14293.98纳克/克,其特征是在污水排放点附近含量最高,并随着距离增加有下降趋势。至于多环芳烃的组成,4 - 6环多环芳烃占主导,而2 - 3环多环芳烃相对较少。聚类分析发现,除城市污水排放外,水动力也影响多环芳烃的分布模式。此外,悬浮颗粒物的含量、悬浮颗粒物中的有机碳和烟灰碳在长江河口及附近沿海地区多环芳烃的分布中也起着重要作用。主成分分析和多环芳烃比值表明,化石燃料的不完全燃烧是沿海地区多环芳烃的主要来源,以及一些石油和石油产品的人为排放。生态风险评估表明,大多数多环芳烃化合物超过了效应范围低值(ER-L)和沉积物质量准则低值(ISQV-L),这可能对长江口生态系统造成一定的潜在损害。