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使用表面活性剂溶液和泡沫修复沙质土壤。

Remediation of sandy soils using surfactant solutions and foams.

作者信息

Couto Hudson J B, Massarani Guilio, Biscaia Evaristo C, Sant'Anna Geraldo L

机构信息

Federal University of Rio de Janeiro, Centro de Tecnologia, COPPE, Rio de Janeiro, Brazil.

出版信息

J Hazard Mater. 2009 May 30;164(2-3):1325-34. doi: 10.1016/j.jhazmat.2008.09.129. Epub 2008 Oct 19.

Abstract

Remediation of sandy soils contaminated with diesel oil was investigated in bench-scale experiments. Surfactant solution, regular foams and colloidal gas aphrons were used as remediation fluids. An experimental design technique was used to investigate the effect of relevant process variables on remediation efficiency. Soils prepared with different average particle sizes (0.04-0.12 cm) and contaminated with different diesel oil contents (40-80 g/kg) were used in experiments conducted with remediation fluids. A mathematical model was proposed allowing for the determination of oil removal rate-constant (k(v)) and oil content remaining in the soil after remediation (C(of)) as well as estimation of the percentage of oil removed. Oil removal efficiencies obtained under the central experimental design conditions were 96%, 88% and 35% for aphrons, regular foams and surfactant solutions, respectively. High removal efficiencies were obtained using regular foams and aphrons, demanding small amounts of surfactant.

摘要

在实验室规模的实验中,对受柴油污染的砂土修复进行了研究。表面活性剂溶液、常规泡沫和胶体气体泡沫被用作修复液。采用实验设计技术来研究相关工艺变量对修复效率的影响。在使用修复液进行的实验中,采用了不同平均粒径(0.04 - 0.12厘米)且受不同柴油含量(40 - 80克/千克)污染的土壤。提出了一个数学模型,用于确定除油速率常数(k(v))和修复后土壤中残留的油含量(C(of))以及估算去除的油的百分比。在中心实验设计条件下,胶体气体泡沫、常规泡沫和表面活性剂溶液的除油效率分别为96%、88%和35%。使用常规泡沫和胶体气体泡沫可获得较高的去除效率,且所需表面活性剂用量较少。

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