通过模拟萘双加氧酶作用的非血红素铁催化剂实现受生物启发的芳烃顺式二羟基化反应。
Bio-inspired arene cis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase.
作者信息
Feng Yan, Ke Chun-Yen, Xue Genqiang, Que Lawrence
机构信息
Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN, USA.
出版信息
Chem Commun (Camb). 2009 Jan 7(1):50-2. doi: 10.1039/b817222f. Epub 2008 Nov 12.
DOI:10.1039/b817222f
PMID:19081995
Abstract
Reported in this paper is the first example of a biomimetic iron complex, (Fe(II)(TPA)(NCMe)(2) (TPA = tris(2-pyridylmethyl)amine), that catalyses the cis-dihydroxylation of an aromatic double bond, mimicking the action of the non-haem iron enzyme naphthalene dioxygenase and shedding light on its possible mechanism of action.
摘要
本文报道了首例仿生铁配合物Fe(II)(TPA)(NCMe)(2)（TPA = 三(2 - 吡啶甲基)胺），它能催化芳香族双键的顺式二羟基化反应，模拟了非血红素铁酶萘双加氧酶的作用，并揭示了其可能的作用机制。
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