2-碘代-N,N-二烷基苯胺氧化物的制备及其X射线晶体结构：首次进入苯并碘恶唑杂环体系
Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline oxides: first entry into the heterocyclic system of benziodoxazole.
作者信息
Zhdankin Viktor V, Nemykin Victor N, Karimov Rashad R, Kazhkenov Zeinul-Gabiden
机构信息
Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota 55812, USA.
出版信息
Chem Commun (Camb). 2008 Dec 14(46):6131-3. doi: 10.1039/b813163e. Epub 2008 Oct 20.
DOI:10.1039/b813163e
PMID:19082096
Abstract
The oxidation of 2-iodo-N,N-dialkylanilines with an excess of dimethyldioxirane in acetone affords 2-iodyl-N,N-dialkylaniline oxides, structural features of which are in agreement with the new heterocyclic system of benziodoxazole.
摘要
在丙酮中，用过量的二甲基二氧杂环丙烷氧化2-碘代-N,N-二烷基苯胺，得到2-碘酰基-N,N-二烷基苯胺氧化物，其结构特征与苯并碘恶唑的新杂环体系一致。
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