Imai Yoshitane, Kamon Kensaku, Murata Katuzo, Harada Takunori, Nakano Yoko, Sato Tomohiro, Fujiki Michiya, Kuroda Reiko, Matsubara Yoshio
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.
Org Biomol Chem. 2008 Oct 7;6(19):3471-5. doi: 10.1039/b808242a. Epub 2008 Jul 10.
A spontaneous resolution chiral fluorescent system is prepared by using 2-anthracenecarboxylic acid, and racemic (rac)-1-phenylethylamine or rac-1-cyclohexylethylamine. Although chiral functional organic materials are usually prepared using chiral molecules, in this system, a chiral organic fluorophore, which exhibits fluorescence in the solid state, is prepared from achiral and rac molecules.