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Preparation of a spontaneous resolution chiral fluorescent system using 2-anthracenecarboxylic acid.

作者信息

Imai Yoshitane, Kamon Kensaku, Murata Katuzo, Harada Takunori, Nakano Yoko, Sato Tomohiro, Fujiki Michiya, Kuroda Reiko, Matsubara Yoshio

机构信息

Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.

出版信息

Org Biomol Chem. 2008 Oct 7;6(19):3471-5. doi: 10.1039/b808242a. Epub 2008 Jul 10.

Abstract

A spontaneous resolution chiral fluorescent system is prepared by using 2-anthracenecarboxylic acid, and racemic (rac)-1-phenylethylamine or rac-1-cyclohexylethylamine. Although chiral functional organic materials are usually prepared using chiral molecules, in this system, a chiral organic fluorophore, which exhibits fluorescence in the solid state, is prepared from achiral and rac molecules.

摘要

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1
Preparation of a spontaneous resolution chiral fluorescent system using 2-anthracenecarboxylic acid.
Org Biomol Chem. 2008 Oct 7;6(19):3471-5. doi: 10.1039/b808242a. Epub 2008 Jul 10.

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