外源性桥联配体的不对称性促进了铁磁和手性[CuII NiII]配合物的组装。
Dissymmetry of an exogenous bridging ligand facilitates the assembly of a ferromagnetic and chiral [CuIINiII] complex.
作者信息
Paital Alok Ranjan, Ribas Joan, Barrios Leoní A, Aromí Guillem, Ray Debashis
机构信息
Department of Chemistry, Indian Institute of Technology, Kharagpur, 721 302, India.
出版信息
Dalton Trans. 2009 Jan 14(2):256-8. doi: 10.1039/b811788h. Epub 2008 Nov 21.
DOI:10.1039/b811788h
PMID:19089004
Abstract
A dissymmetric exogenous bridging ligand provides access to a heterometallic [NiIICuII] complex held together by a symmetric compartmental ligand; the complex is chiral and, as a result of ferromagnetic coupling, it exhibits an S=3/2 spin ground state, the EPR of which has been simulated.
摘要
一种不对称的外源桥连配体可用于构建由对称隔室配体维系的异金属[NiII CuII]配合物；该配合物具有手性，由于铁磁耦合作用，它呈现出S = 3/2的自旋基态，并且已对其电子顺磁共振进行了模拟。
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