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[激光诱导击穿光谱的理论及影响因素]

[The theory and the influential factors of laser induced breakdown spectroscopy].

作者信息

Yuan Dong-qing, Zhou Ming, Liu Chang-long, Yan Feng, Dai Juan, Ren Nai-fei

机构信息

Center for Photo Manu-Facturing Science and Technology, Jiangsu University, Zhenjiang 212013, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Sep;28(9):2019-23.

Abstract

The laser-induced breakdown spectroscopy (LIBS) technique, due to its lack of pretreatment of the material and the speed of analysis, has shown a great potential for a wide range of industrial applications. The current situation of application and study of LIBS are reviewed. Meanwhile, the laser used to explode the Cr and Co film had a pulse duration of 10 ns, the highest single pulse energy was 50 mJ at a repetition rate of 20 Hz, and a wavelength of 1064 nm. When the excitation energy was less than 10 mJ, there was little difference in spectral signal excited by different energy for Cr film. Otherwise, the signal showed obvious change when excitation energy was higher than 10 mJ. The principle, characters, history and recent trend of LIBS were introduced systematically. The factors influencing LIBS performances, including the characteristic of laser, delay time, experiment setting, the kind and the pressure of surrounding. Gas, single or dual pulse, and the analysis method were analyzed.

摘要

激光诱导击穿光谱(LIBS)技术由于无需对材料进行预处理且分析速度快,在广泛的工业应用中显示出巨大潜力。本文综述了LIBS的应用和研究现状。同时,用于烧蚀Cr和Co薄膜的激光脉冲持续时间为10 ns,最高单脉冲能量为50 mJ,重复频率为20 Hz,波长为1064 nm。当激发能量小于10 mJ时,不同能量激发的Cr薄膜光谱信号差异不大。否则,当激发能量高于10 mJ时,信号会出现明显变化。系统介绍了LIBS的原理、特点、发展历程和最新趋势。分析了影响LIBS性能的因素,包括激光特性、延迟时间、实验装置、周围气体的种类和压力、单脉冲或双脉冲以及分析方法。

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