Vilmercati Paolo, Castellarin-Cudia Carla, Gebauer Ralph, Ghosh Prasenjit, Lizzit Silvano, Petaccia Luca, Cepek Cinzia, Larciprete Rosanna, Verdini Alberto, Floreano Luca, Morgante Alberto, Goldoni Andrea
Sincrotrone Trieste S.C.p.A., s.s. 14 km 163.5 in Area Science Park, 34012 Trieste, Italy.
J Am Chem Soc. 2009 Jan 21;131(2):644-52. doi: 10.1021/ja806914g.
The peculiar electrochemical and photophysical properties of porphyrin and fullerene molecules make them promising candidates for the construction of two- and three-dimensional organic-based materials. An important question is how pristine fullerene and porphyrin will organize when deposited on surfaces via in vacuum molecular beam evaporation. Here we show that codeposition of C(70) and Zn-tetraphenyl-porphyrin (ZnTPP) induces the self-assembly of electron-rich flat aromatic molecules at the curved surface of C(70), thus enhancing the chromophore interaction and forming a supramolecular multilayer donor-acceptor structure. While the ground-state electronic spectra almost reflect a simple summation of ZnTPP and C(70) components, the excited-state electrons at the porphyrin macrocycle can rapidly delocalize to the fullerene. The excited charge transfer time scale is faster than 1-2 fs, as shown by resonant photoemission for the core-excited charges.
