Leithe-Jasper A, Schnelle W, Geibel C, Rosner H
Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Strasse 40, 01187 Dresden, Germany.
Phys Rev Lett. 2008 Nov 14;101(20):207004. doi: 10.1103/PhysRevLett.101.207004.
In the strontium iron-cobalt arsenides SrFe2-xCoxAs2 (0.2 < or = x < or = 0.4) superconductivity with T_{c} up to 20 K is observed in magnetic susceptibility, electrical resistivity, and specific heat data. This first observation of bulk superconductivity induced by electron doping in this family of compounds-despite strong disorder in the Fe-As layer-favors an itinerant electronic theory in contrast to the strongly correlated cuprates and renders a p- or d-wave pairing unlikely. The magnetic ordering present in SrFe2As2 is rapidly suppressed by substitution of Fe by Co. Density functional theory calculations show that this is due to a rigid downshift of the Fe-3d_{x;{2}-y;{2}}-related band edge in the density of states.
在锶铁钴砷化物SrFe₂₋ₓCoₓAs₂(0.2 ≤ x ≤ 0.4)中,通过磁化率、电阻率和比热数据观测到了超导转变温度Tc高达20K的超导性。尽管Fe-As层存在强烈无序,但在该化合物家族中首次观测到由电子掺杂诱导的体超导性,这与强关联铜酸盐形成对比,支持巡游电子理论,且不太可能是p波或d波配对。通过用Co替代Fe,SrFe₂As₂中存在的磁有序被迅速抑制。密度泛函理论计算表明,这是由于态密度中与Fe-3dₓ₂₋y₂相关的能带边缘发生刚性下移所致。