Department of Physics, Okayama University, Okayama 700-8530, Japan.
Sci Rep. 2013;3:1478. doi: 10.1038/srep01478.
Co-doping of lanthanum and phosphorus in CaFe₂As₂ induces superconductivity at 45 K. This superconducting transition temperature is higher than the 38 K transition in Ba₁-xKxFe₂As₂, which is the maximum found thus far among the 122 phases. Superconductivity with a substantial shielding volume fraction was observed at 0.12 ≤ x ≤ 0.18 and y = 0.06 in Ca₁-xLaxFe₂(As₁-yPy)₂. The superconducting phase of the present system seems to be not adjacent to an antiferromagnetic phase.
镧和磷共掺杂 CaFe₂As₂ 诱导出 45 K 的超导性。这个超导转变温度高于 Ba₁-xKxFe₂As₂ 的 38 K 转变温度,是迄今为止在 122 相中发现的最高温度。在 Ca₁-xLaxFe₂(As₁-yPy)₂ 中,当 0.12 ≤ x ≤ 0.18 且 y = 0.06 时,观察到具有大量屏蔽体积分数的超导性。本系统的超导相似乎与反铁磁相不相邻。