C80Cl12：手性D2-C80异构体的氯衍生物——卤素原子加成模式的经验原理

C80Cl12: a chlorine derivative of the chiral D2-C80 isomer--empirical rationale of halogen-atom addition pattern.

作者信息

Simeonov Kalin S, Amsharov Konstantin Yu, Jansen Martin

机构信息

Max Planck Institute for Solid State Research, Heisenbergstrasse 1, 70569 Stuttgart, Germany.

出版信息

Chemistry. 2009;15(8):1812-5. doi: 10.1002/chem.200802198.

DOI:10.1002/chem.200802198

PMID:19115288

Abstract

Welcome to the family! The constitution of the chiral D(2)-C(80) fullerene has been confirmed through single-crystal X-ray analysis of the chlorinated C(80)Cl(12). The addition pattern of the chlorine atoms in the structure of C(80)Cl(12) together with other structures of halogenated higher fullerenes is discussed. A stepwise principle of higher fullerene reactivity is proposed. Unusual short intermolecular chlorine-chlorine contacts are reported.

摘要

欢迎加入这个大家庭！通过对氯化C(80)Cl(12)进行单晶X射线分析，已证实了手性D(2)-C(80)富勒烯的结构。讨论了C(80)Cl(12)结构中氯原子的加成模式以及其他卤化高阶富勒烯的结构。提出了高阶富勒烯反应性的逐步原理。报告了异常短的分子间氯-氯接触。