C(76)Cl(34)：具有螺旋结构的本征手性富勒烯的高度氯化。

C(76)Cl(34): high chlorination of the inherent chiral fullerene with a helical configuration.

机构信息

State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

出版信息

Inorg Chem. 2010 Apr 5;49(7):3089-91. doi: 10.1021/ic902442p.

DOI:10.1021/ic902442p

PMID:20222665

Abstract

As the smallest chiral fullerene in conformity with the Isolated Pentagon Rule (IPR), D(2)-symmetric C(76) has been chlorinated with iodine monochloride to form C(76)Cl(34), a highly chlorinated derivative. Its structure with the chiral cage enwrapped by a helical chlorine pattern has been established using single-crystal X-ray diffraction analysis. The high chlorination and its implication for constructing novel chiral fullerene-based materials are discussed.

摘要

作为符合孤立五边形规则（IPR）的最小手性富勒烯，D(2)-对称 C(76) 已被一氯化碘氯化，形成高度氯化的衍生物 C(76)Cl(34)。其结构采用单晶 X 射线衍射分析确定，具有由螺旋氯图案包裹的手性笼。讨论了高氯化及其对手性富勒烯基材料构建的意义。