由VO(acac)(2)引发的环氧缩醛化反应触发的对pectenotoxin-4的CDE环系统的一种新方法。
A novel approach to the CDE ring system of pectenotoxin-4 triggered by VO(acac)(2)-induced epoxy-acetalization.
作者信息
Carley Sarah, Brimble Margaret A
机构信息
Department of Chemistry, The University of Auckland, 23 Symonds Street, Auckland, New Zealand.
出版信息
Org Lett. 2009 Feb 5;11(3):563-6. doi: 10.1021/ol8025457.
PMID:19117488
Abstract
A novel approach to the CDE fragment of pectenotoxin-4 is described wherein the bicyclic acetal is constructed via a cascade cyclization induced by VO(acac)(2) epoxidation of a homoallylic alcohol.
摘要
描述了一种制备pectenotoxin-4的CDE片段的新方法，其中双环缩醛是通过VO(acac)(2)对高烯丙醇的环氧化引发的级联环化反应构建的。
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