Duan Chenlong, Wen Xuefeng, Shi Changsheng, Zhao Yuemin, Wen Baofeng, He Yaqun
School of Chemical Engineering and Technology, China University of Mining & Technology, Xuzhou 221008, PR China.
J Hazard Mater. 2009 Jul 15;166(1):478-82. doi: 10.1016/j.jhazmat.2008.11.060. Epub 2008 Nov 27.
Research on the recycling of waste printed circuit boards (PCB) is at the forefront of environmental pollution prevention and resource recycling. To effectively crush waste PCB and to solve the problem of secondary pollution from fugitive odors and dust created during the crushing process, a wet impacting crusher was employed to achieve comminution liberation of the PCB in a water medium. The function of water in the crushing process was analyzed. When using slippery hammerheads, a rotation speed of 1470 rpm, a water flow of 6m(3)/h and a sieve plate aperture of 2.2mm, 95.87% of the crushed product was sized less than 1mm. 94.30% of the metal was in this grade of product. Using smashed material graded -1mm for further research, a Falcon concentrator was used to recover the metal from the waste PCB. Engineering considerations were the liberation degree, the distribution ratio of the metal and a way to simplify the technology. The separation mechanism for fine particles of different densities in a Falcon concentrator was analyzed in detail and the separation process in the segregation and separation zones was deduced. Also, the magnitude of centrifugal acceleration, the back flow water pressure and the feed slurry concentration, any of which might affect separation results, were studied. A recovery model was established using Design-Expert software. Separating waste PCB, crushed to -1mm, with the Falcon separator gave a concentrated product graded 92.36% metal with a recovery of 97.05%. To do this the reverse water pressure was 0.05 MPa, the speed transducer frequency was set at 30 Hz and the feed density was 20 g/l. A flow diagram illustrating the new technique of wet impact crushing followed by separation with a Falcon concentrator is provided. The technique will prevent environmental pollution from waste PCB and allow the effective recovery of resources. Water was used as the medium throughout the whole process.
废旧印刷电路板(PCB)回收研究处于环境污染防治和资源回收利用的前沿。为有效粉碎废旧PCB并解决粉碎过程中产生的逃逸气味和粉尘造成的二次污染问题,采用湿式冲击破碎机在水介质中实现PCB的粉碎解离。分析了水在粉碎过程中的作用。使用滑锤头时,转速为1470转/分钟,水流量为6立方米/小时,筛板孔径为2.2毫米,95.87%的粉碎产物粒度小于1毫米。94.30%的金属在该粒度等级的产物中。使用粒度分级为-1毫米的粉碎物料进行进一步研究,采用Falcon选矿机从废旧PCB中回收金属。工程考虑因素包括解离度、金属的分配比以及简化工艺的方法。详细分析了Falcon选矿机中不同密度细颗粒的分离机理,并推导了分选和分离区域的分离过程。还研究了可能影响分离结果的离心加速度大小、回流水压和给料矿浆浓度。使用Design-Expert软件建立了回收模型。用Falcon分离器分离粒度为-1毫米的废旧PCB,得到金属品位为92.36%的精矿,回收率为97.05%。为此,反向水压为0.05兆帕,速度传感器频率设置为30赫兹,给料密度为20克/升。提供了一个流程图,说明了湿式冲击破碎后用Falcon选矿机分离的新技术。该技术将防止废旧PCB造成的环境污染,并实现资源的有效回收。整个过程均以水为介质。