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使用浸没式厌氧膜生物反应器(SAMBR)处理含盐污水:添加活性炭和沼气曝气时间的影响

Saline sewage treatment using a submerged anaerobic membrane reactor (SAMBR): effects of activated carbon addition and biogas-sparging time.

作者信息

Vyrides I, Stuckey D C

机构信息

Department of Chemical Engineering and Chemical Technology, Imperial College London, South Kensington, London SW7 2AZ, UK.

出版信息

Water Res. 2009 Mar;43(4):933-42. doi: 10.1016/j.watres.2008.11.054. Epub 2008 Dec 24.

Abstract

This study investigated the performance of a submerged anaerobic membrane reactor (SAMBR) treating saline sewage under fluctuating concentrations of salinity (0-35g NaCl/L), at 8 and 20h HRT, with fluxes ranging from 5-8litres per square metre per hour (LMH). The SAMBRs attained a 99% removal of Dissolved Organic Carbon (DOC) with 35g NaCl/L, while removal inside the reactor was significantly lower (40-60% DOC). Even with a sudden drop in salinity overall removal recovered quickly, while the recovery inside the reactor took place at a slower rate. This highlights the positive effect of the membrane in preventing the presence of high molecular weight organics in the effluent while also retaining biomass inside the reactor so that they can rapidly acclimatize to salinity. The reduction of continuous biogas sparging to intervals of 10min ON and 5min OFF resulted in a slight increase in transmembrane pressure (TMP) by 0.025bar, but also resulted in an increase in effluent DOC removal and inside the SAMBR by 10% and 20%, respectively. The addition of powdered activated carbon (PAC) resulted in a decrease in the TMP by 0.070bar, and an increase in DOC removal in the reactor and effluent by 30% and 5%, respectively. The PAC dramatically decreased the high molecular weight organics in the reactor over a period of 72h. SEM pictures of the membrane and biomass before and after addition of PAC revealed a remarkable reduction of flocks on the membrane surface, and a reduction inside the reactor of soluble microbial products (SMPs). Finally, Energy Dispersive X-ray (EDX) analysis of the membranes pores and biofilm highlighted the absence of organic matter in the inner pores of the membrane.

摘要

本研究调查了浸没式厌氧膜生物反应器(SAMBR)在盐度波动(0 - 35g NaCl/L)、水力停留时间(HRT)分别为8小时和20小时、通量为每平方米每小时5 - 8升(LMH)的条件下处理含盐污水的性能。当盐度为35g NaCl/L时,SAMBR对溶解有机碳(DOC)的去除率达到99%,而反应器内的去除率则显著较低(DOC为40 - 60%)。即使盐度突然下降,总体去除率也能迅速恢复,而反应器内的恢复速度则较慢。这突出了膜在防止高分子量有机物进入出水以及将生物质保留在反应器内以便它们能迅速适应盐度方面的积极作用。将连续沼气曝气减少为10分钟开和5分钟关的间隔,导致跨膜压力(TMP)略有增加,增加了0.025巴,但同时也使出水DOC去除率和SAMBR内的DOC去除率分别提高了10%和20%。添加粉末活性炭(PAC)使TMP降低了0.070巴,反应器内和出水中的DOC去除率分别提高了30%和5%。在72小时内,PAC显著降低了反应器内的高分子量有机物。添加PAC前后膜和生物质的扫描电子显微镜(SEM)图片显示膜表面的絮状物显著减少,反应器内的可溶性微生物产物(SMPs)也有所减少。最后,对膜孔和生物膜的能量色散X射线(EDX)分析表明膜的内孔中不存在有机物。

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