1,4 - 二氢吡啶的氢化物供体能力：与π亲核试剂和硼氢化物阴离子的比较
Hydride-donor abilities of 1,4-dihydropyridines: a comparison with pi nucleophiles and borohydride anions.
作者信息
Richter Dorothea, Mayr Herbert
机构信息
Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13 (Haus F), 81377 München, Germany.
出版信息
Angew Chem Int Ed Engl. 2009;48(11):1958-61. doi: 10.1002/anie.200804263.
PMID:19185030
Abstract
How are dihydropyridines like indoles? Both groups of compounds have similar nucleophilicity parameters N and are therefore suitable substrates for iminium-catalyzed reactions of alpha,beta-unsaturated aldehydes. The N parameters of 1,4-dihydropyridines were derived from the rates of hydride transfer reactions to benzhydrylium ions (see scheme).
摘要
二氢吡啶与吲哚有何相似之处？这两类化合物具有相似的亲核性参数N，因此都是α,β-不饱和醛亚胺催化反应的合适底物。1,4-二氢吡啶的N参数源自氢负离子向二苯甲基正离子转移反应的速率（见反应式）。
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