Scheschkewitz David
Department of Chemistry, Imperial College London, South Kensington Campus, UK.
Chemistry. 2009 Mar 2;15(11):2476-85. doi: 10.1002/chem.200801968.
E=Si transfer: Anionic compounds capable of transferring a silicon-containing double bond are reviewed (see figure), particularly reagents with Si=Si moieties (Tip=2,4,6-iPr(3)C(6)H(2), M=Li, Na, K) and their applications towards main-group and transition-metal electrophiles, as well as their reactivity towards organic compounds. A few recently reported derivatives with Si=C (Ad=1-adamantyl) and Si=P moieties are included for completeness.Anionic compounds capable of transferring a silicon double bond are summarized following an introduction to the differences between alkenes and their heavier homologues. The main focus is on reagents with Si=Si moieties and their applications towards main-group and transition-metal electrophiles, as well as their reactivity towards organic compounds, but a few recently reported derivatives with Si=C and Si=P bonds are also included.
E=Si转移：对能够转移含硅双键的阴离子化合物进行了综述（见图），特别是含有Si=Si部分的试剂（Tip=2,4,6-异丙基(3)苯，M=Li、Na、K）及其对主族和过渡金属亲电试剂的应用，以及它们与有机化合物的反应性。为完整起见，还包括了一些最近报道的含有Si=C（Ad=1-金刚烷基）和Si=P部分的衍生物。在介绍了烯烃与其较重同系物之间的差异之后，对能够转移硅双键的阴离子化合物进行了总结。主要重点是含有Si=Si部分的试剂及其对主族和过渡金属亲电试剂的应用，以及它们与有机化合物的反应性，但也包括了一些最近报道的含有Si=C和Si=P键的衍生物。
