Shundo Atsuomi, Hill Jonathan P, Ariga Katsuhiko
World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS) 1-1 Namiki, Tsukuba 305-0044, Japan.
Chemistry. 2009 Mar 2;15(11):2486-90. doi: 10.1002/chem.200802469.
Written in the gel: A fluoride-writable memory system has been demonstrated by using two porphyrin derivatives. Structural modification enabled both volatile and nonvolatile modes. For both porphyrins, fluorescence is quenched by addition of F(-) with only one of the derivatives returning to its initial fluorescent state following removal of F(-) (see scheme). Nonvolatile behaviour is based on anion-induced conversion from porphyrin to oxoporphyrinogen.
通过使用两种卟啉衍生物展示了一种氟化物可写入的存储系统。结构修饰实现了挥发性和非挥发性模式。对于这两种卟啉，添加F⁻会猝灭荧光，只有一种衍生物在去除F⁻后恢复到其初始荧光状态（见图）。非挥发性行为基于阴离子诱导的从卟啉到氧化卟啉原的转变。
