Lokesh S V, Sherigara B S, Naik H S Bhojya, Shivaraj Y, Satpati A K
Department of PG Studies and Research in Industrial Chemistry, School of Chemical Sciences, Kuvempu University, Shankaraghatta -577 451, Shimoga, Karnataka, India.
J Environ Sci Eng. 2008 Jan;50(1):69-74.
Trace metal levels in selected medicinal plant leaves from Western Ghats, Karnataka, India were studied A method for the determination of Zinc, Copper, Lead and Cadmium simultaneously in the pH of 4.5 in citrate buffer, and Cobalt and Nickel simultaneously in the pH 9.2 in ammonia buffer medium has been optimized. Electrochemical method, Differential Pulse Anodic Stripping Voltammetry (DPASV) has been used for quantification. The optimized procedure has been successfully applied for the determination of the above-mentioned metal ions in some medicinally important plant leaves from Western Ghats, Karnataka, India. The concentrations of trace metals in the medicinal plant samples were found to be in the ranges: 15.61-20.71 mg g(-1) for copper, 0.056-0.10 mg g(-1) for cadmium, 0.91-1.81 mg g(-1) for lead, 0.42-0.96 mg g(-1) for nickel, 1.21-1.97 mg g(-1) for cobalt and 23.29-32.52 mg g(-1) for zinc. The effect of pH, deposition time and potential has been studied and optimized. The study reveals that all the trace metals are well within the maximum permissible limits, therefore, medicinal plants of this region are very much suitable for medicinal use. The results are compared with the data obtained by atomic absorption spectroscopy.
对印度卡纳塔克邦西高止山脉选定药用植物叶片中的痕量金属水平进行了研究。已优化了一种在柠檬酸盐缓冲液pH值为4.5时同时测定锌、铜、铅和镉,以及在氨缓冲介质pH值为9.2时同时测定钴和镍的方法。采用电化学方法——差分脉冲阳极溶出伏安法(DPASV)进行定量分析。该优化程序已成功应用于测定印度卡纳塔克邦西高止山脉一些具有重要药用价值的植物叶片中的上述金属离子。药用植物样品中痕量金属的浓度范围为:铜15.61 - 20.71 mg g(-1)、镉0.056 - 0.10 mg g(-1)、铅0.91 - 1.81 mg g(-1)、镍0.42 - 0.96 mg g(-1)、钴1.21 - 1.97 mg g(-1)、锌23.29 - 32.52 mg g(-1)。研究并优化了pH值、沉积时间和电位的影响。研究表明,所有痕量金属均在最大允许限值范围内,因此,该地区的药用植物非常适合药用。将结果与原子吸收光谱法获得的数据进行了比较。