Qiu Shuifa, Wei Yunyang, Liu Guosheng
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academic of Science, 354 Fengling Road, Shanghai, 200032, China.
Chemistry. 2009;15(12):2751-4. doi: 10.1002/chem.200802381.
Taking the air! A Pd(II)-catalyzed intramolecular hydroamination of allenes coupled to alcohol oxidation has been developed. This reaction is performed by using a nitrogen-based ligand under aerobic conditions, under which the molecular oxygen is used as the terminal oxidant for the reoxidation of Pd(0) species to complete the catalytic cycle.
呼吸新鲜空气！已开发出一种钯（II）催化的丙二烯分子内氢胺化反应与醇氧化反应相耦合的反应。该反应在有氧条件下使用含氮配体进行，在此条件下，分子氧用作将钯（0）物种再氧化以完成催化循环的终端氧化剂。
