Tripkovic D V, Strmcnik D, van der Vliet D, Stamenkovic V, Markovic N M
Materials Science Division, Argonne National Laboratory, University of Chicago, Argonne, Illinois 60439, USA.
Faraday Discuss. 2008;140:25-40; discussion 93-112. doi: 10.1039/b803714k.
Some issues of the current state of understanding in the surface electrochemistry are discussed, with emphases on the role of specifically adsorbing anions in hydrogen adsorption and oxide formation, adsorption and ordering of molecular adsorbates and metal ions, metal deposition, restructuring and stability of surface atoms, and kinetics of electrochemical reactions.
讨论了当前表面电化学领域理解方面的一些问题,重点关注了特异性吸附阴离子在氢吸附和氧化物形成、分子吸附质和金属离子的吸附与有序排列、金属沉积、表面原子的重构与稳定性以及电化学反应动力学中的作用。