逐步增长聚合和链式增长聚合制备的聚合物之间的无规化反应：1,4-聚丁二烯与含烯烃聚酯之间的大分子交叉复分解反应
Scrambling reaction between polymers prepared by step-growth and chain-growth polymerizations: macromolecular cross-metathesis between 1,4-polybutadiene and olefin-containing polyester.
作者信息
Otsuka Hideyuki, Muta Takatoshi, Sakada Masahide, Maeda Takeshi, Takahara Atsushi
机构信息
Institute for Materials Chemistry and Engineering, Kyushu University, Motooka, Nishi-ku, Fukuoka 819-0395, Japan.
出版信息
Chem Commun (Camb). 2009 Mar 7(9):1073-5. doi: 10.1039/b818014h. Epub 2009 Jan 5.
DOI:10.1039/b818014h
PMID:19225640
Abstract
Controlled hybridization of olefin-containing polymers prepared by two different polymerization methods, step-growth polymerization and chain-growth polymerization, was accomplished by macromolecular olefin cross-metathesis.
摘要
通过大分子烯烃复分解反应，实现了由两种不同聚合方法（逐步增长聚合和链式增长聚合）制备的含烯烃聚合物的可控杂交。
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