由单膦基和双膦基二茂铁与B(C6F5)3衍生的受阻路易斯酸碱对激活H2 。
Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3.
作者信息
Ramos Alberto, Lough Alan J, Stephan Douglas W
机构信息
Department of Chemistry, University of Toronto, 80 St George St, Toronto, Ontario, CanadaM5S 3H6.
出版信息
Chem Commun (Camb). 2009 Mar 7(9):1118-20. doi: 10.1039/b819525k. Epub 2009 Jan 12.
DOI:10.1039/b819525k
PMID:19225655
Abstract
Mono- and bis-phosphinoferrocenes are shown to react as frustrated Lewis pairs (FLPs) to effect nucleophilic aromatic substitution on B(C(6)F(5))(3) and/or activate H(2) to form ferrocenylphosphonium borates.
摘要
单膦基和双膦基二茂铁被证明可作为受阻路易斯酸碱对（FLPs）发生反应，以实现对B(C(6)F(5))(3)的亲核芳香取代反应和/或活化H(2)以形成二茂铁基鏻硼酸盐。
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