2-三苯甲基吡咯烷催化醛的直接不对称苯甲酰氧基化反应。
Direct asymmetric benzoyloxylation of aldehydes catalyzed by 2-tritylpyrrolidine.
作者信息
Kano Taichi, Mii Haruka, Maruoka Keiji
机构信息
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.
出版信息
J Am Chem Soc. 2009 Mar 18;131(10):3450-1. doi: 10.1021/ja809963s.
PMID:19227974
Abstract
A direct asymmetric benzoyloxylation of aldehydes with benzoyl peroxide was found to be catalyzed by (S)-2-(triarylmethyl)pyrrolidines (S)-2. This method provides a new approach for the preparation of optically active alpha-benzoyloxyaldehydes as useful chiral building blocks.
摘要
发现（S）-2-（三芳基甲基）吡咯烷（S）-2可催化用过氧化苯甲酰对醛进行直接不对称苯甲酰氧基化反应。该方法为制备具有光学活性的α-苯甲酰氧基醛提供了一种新途径，α-苯甲酰氧基醛是有用的手性结构单元。
Zotero 插件