Del Mundo Dacera Dominica, Babel Sandhya, Parkpian Preeda
Environmental Technology Program, School of Bio-Chemical Engineering and Technology, Sirindhorn International Institute of Technology (SIIT), Thammasat University, Pathumthani, Thailand.
J Hazard Mater. 2009 Aug 15;167(1-3):866-72. doi: 10.1016/j.jhazmat.2009.01.064. Epub 2009 Feb 18.
The suitability for land application of anaerobically digested sewage sludge treated with naturally fermented and Aspergillus niger (A. niger) fermented raw liquid from pineapple wastes, in terms of changes in the forms and amount of heavy metals and nutrient and pathogen content, were investigated in this study. Leaching studies for fermented liquid at optimum conditions (pH and contact time with best metal removal efficiencies) were carried out for the removal of Cd, Cr, Cu, Pb, Ni and Zn from sewage sludge, with citric acid as a reference. Using the same sludge before and after leaching, sequential fractionation studies were done to observe the effect of treatment on the forms of metals in sludge and their mobility and bioavailability. Results of laboratory scale studies revealed that leaching with all extractants at selected optimum conditions resulted in a decrease in heavy metals and pathogen content of the treated sludge, presence of sufficient amount of nutrients (nitrogen and phosphorous) and dominance of residual fractions in most metals, with sludge treated with A. niger, having the best quality. The results, therefore, indicate the high potential of the treated sludge for land application, with no harm from heavy metals released and no toxicity to the soil and groundwater.
本研究考察了用菠萝废弃物自然发酵液和黑曲霉发酵液处理的厌氧消化污水污泥在土地施用方面的适用性,涉及重金属形态和含量、养分及病原体含量的变化。以柠檬酸为参照,在最佳条件(pH值和接触时间,此时金属去除效率最佳)下对发酵液进行浸出研究,以去除污水污泥中的镉、铬、铜、铅、镍和锌。使用浸出前后的相同污泥进行连续分级研究,以观察处理对污泥中金属形态及其迁移性和生物有效性的影响。实验室规模研究结果表明,在选定的最佳条件下用所有萃取剂浸出,均可降低处理后污泥中的重金属和病原体含量,污泥中存在足够量的养分(氮和磷),且大多数金属以残留态为主,其中用黑曲霉处理的污泥质量最佳。因此,结果表明处理后的污泥具有很高的土地施用潜力,不会释放重金属造成危害,也不会对土壤和地下水产生毒性。