二维和三维中杂环轮烯的超分子组装

Supramolecular assembly of heterocirculenes in 2D and 3D.

作者信息

Ivasenko Oleksandr, Macleod Jennifer M, Chernichenko Konstantin Yu, Balenkova Elizabeth S, Shpanchenko Roman V, Nenajdenko Valentine G, Rosei Federico, Perepichka Dmitrii F

机构信息

Department of Chemistry, McGill University, 801 Sherbrooke str. West, Montreal, Canada H3A 2K6.

出版信息

Chem Commun (Camb). 2009 Mar 14(10):1192-4. doi: 10.1039/b819532c. Epub 2009 Jan 6.

DOI:10.1039/b819532c

PMID:19240870

Abstract

The results of a high-resolution ambient STM study of 'sulflower' (octathio[8]circulene) and 'selenosulflower' (sym-tetraselena-tetrathio[8]circulene) molecules, immobilized in a hydrogen-bonded matrix of trimesic acid (TMA) at the solid-liquid interface, are compared with the STM and X-ray structure of separate host and guest 2D and 3D crystals, respectively.

摘要

将“硫代花”（八硫代[8]轮烯）和“硒代硫代花”（对称四硒代四硫代[8]轮烯）分子在固液界面固定于均苯三甲酸（TMA）的氢键基质中进行高分辨率环境扫描隧道显微镜（STM）研究的结果，分别与单独的主体和客体二维及三维晶体的STM和X射线结构进行了比较。