金属酞菁配合物Cr(TBPC)OTf：一种用于环氧化物区域和立体选择性重排为醛的高效、可循环使用的路易斯酸催化剂。
Metallophthalocyanine complex, Cr(TBPC)OTf: an efficient, recyclable Lewis acid catalyst in the regio- and stereoselective rearrangement of epoxides to aldehydes.
作者信息
Suda Kohji, Nakajima Shin-Ichiro, Satoh Yasumi, Takanami Toshikatsu
机构信息
Meiji Pharmaceutical University, 2-522-1, Noshio, Kiyose, Tokyo 204-8588, Japan.
出版信息
Chem Commun (Camb). 2009 Mar 14(10):1255-7. doi: 10.1039/b820948k. Epub 2009 Jan 20.
DOI:10.1039/b820948k
PMID:19240891
Abstract
The metallophthalocyanine complex Cr(TBPC)OTf works as a highly efficient, recyclable Lewis acid catalyst for the regio- and stereoselective rearrangements of epoxides to aldehydes.
摘要
金属酞菁配合物Cr(TBPC)OTf作为一种高效、可循环使用的路易斯酸催化剂，用于环氧化物区域和立体选择性重排为醛。
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