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In situ cyclodehydration of iminodiacetic acid into 2,5-diketopiperazine-1,4-diacetate in lanthanide-based coordination polymers.

作者信息

Kong Xiang-Jian, Zhuang Gui-Lin, Ren Yan-Ping, Long La-Sheng, Huang Rong-Bin, Zheng Lan-Sun

机构信息

State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.

出版信息

Dalton Trans. 2009 Mar 14(10):1707-9. doi: 10.1039/b819792j. Epub 2009 Jan 26.

Abstract

The reaction of iminodiacetic acid with Ln2O3 (Ln = Dy, Ho, Er, Yb) under hydrothermal conditions generate a series of 3D lanthanide-based coordination polymers, in which, the iminodiacetic acid (IDA) was transformed into a 2,5-diketopiperazine-1,4-diacetate.

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