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高压高温下致密氙的电离与状态方程

Ionization and equation of state of dense xenon at high pressures and high temperatures.

作者信息

Chen Q F, Cai L C, Gu Y J, Gu Y

机构信息

Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, P.O. Box 919-102, Mianyang, Sichuan, People's Republic of China.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Jan;79(1 Pt 2):016409. doi: 10.1103/PhysRevE.79.016409. Epub 2009 Jan 22.

Abstract

The ionization degree and equation of state of dense xenon plasma were calculated by using self-consistent fluid variational theory for temperature of 4-30kK and density of 0.01-8.5gcm;{3} . The dense fluid xenon will be ionized at high pressures and temperatures. The ionization energy of xenon will be lowered due to the interactions among all particles of Xe, Xe+ , Xe2+ , and e . The ionization degree is obtained from nonideal ionization equilibrium, taking into account the correlative contributions to the chemical potential which is determined self-consistently by the free energy function. The composition of xenon has been calculated with given densities and temperatures in the region of partial ionization. The calculated results show a pressure softening regime at the onset of ionization. Comparison is performed with available shock-wave experiments and other theoretical calculations.

摘要

利用自洽流体变分理论,计算了温度为4 - 30kK、密度为0.01 - 8.5g/cm³的致密氙等离子体的电离度和状态方程。致密流体氙在高压和高温下会发生电离。由于Xe、Xe⁺、Xe²⁺和e所有粒子之间的相互作用,氙的电离能会降低。电离度是从非理想电离平衡中获得的,其中考虑了对化学势的相关贡献,而化学势由自由能函数自洽确定。在部分电离区域,已根据给定的密度和温度计算了氙的组成。计算结果表明,在电离开始时存在压力软化机制。并与现有的冲击波实验和其他理论计算进行了比较。

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