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玻璃形成材料中慢动力学的渗流模型。

Percolation model for slow dynamics in glass-forming materials.

作者信息

Lois Gregg, Blawzdziewicz Jerzy, O'Hern Corey S

机构信息

Department of Physics, Department of Mechanical Engineering, Yale University, New Haven, Connecticut 06520-8284, USA.

出版信息

Phys Rev Lett. 2009 Jan 9;102(1):015702. doi: 10.1103/PhysRevLett.102.015702. Epub 2009 Jan 6.

Abstract

We identify a link between the glass transition and percolation of regions of mobility in configuration space. We find that many hallmarks of glassy dynamics, for example, stretched-exponential response functions and a diverging structural relaxation time, are consequences of the critical properties of mean-field percolation. Specific predictions of the percolation model include the range of possible stretching exponents 1/3< or =beta< or =1 and the functional dependence of the structural relaxation time tau_{alpha} and exponent beta on temperature, density, and wave number.

摘要

我们确定了玻璃化转变与构型空间中迁移率区域渗流之间的联系。我们发现,玻璃态动力学的许多特征,例如拉伸指数响应函数和发散的结构弛豫时间,都是平均场渗流临界性质的结果。渗流模型的具体预测包括可能的拉伸指数范围1/3≤β≤1,以及结构弛豫时间τα和指数β对温度、密度和波数的函数依赖性。

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