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玻璃形成液体中的平衡与非平衡涨落。

Equilibrium and nonequilibrium fluctuations in a glass-forming liquid.

作者信息

Parsaeian Azita, Castillo Horacio E

机构信息

Department of Physics and Astronomy, Ohio University, Athens, Ohio, 45701, USA.

出版信息

Phys Rev Lett. 2009 Feb 6;102(5):055704. doi: 10.1103/PhysRevLett.102.055704.

Abstract

Glass-forming liquids display strong fluctuations-dynamical heterogeneities-near their glass transition. By numerically simulating a binary Weeks-Chandler-Andersen liquid and varying both temperature and time scale, we investigate the probability distributions of two kinds of local fluctuations in the nonequilibrium (aging) regime and in the equilibrium regime, and find them to be very similar in the two regimes and across temperatures. We also observe that, when appropriately rescaled, the integrated dynamic susceptibility is very weakly dependent on temperature and very similar in both regimes.

摘要

形成玻璃的液体在其玻璃化转变附近表现出强烈的涨落——动力学非均匀性。通过对二元韦克斯-钱德勒-安德森液体进行数值模拟,并改变温度和时间尺度,我们研究了非平衡(老化)态和平衡态下两种局部涨落的概率分布,发现它们在这两种状态以及不同温度下都非常相似。我们还观察到,经过适当的重新标度后,积分动态磁化率对温度的依赖性非常弱,并且在两种状态下非常相似。

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