Equilibrium route to colloidal gelation: mixtures of hard-sphere-like colloids.

The binodals and the nonergodicity lines of a binary mixture of hard-sphere-like particles with a large size ratio are computed for studying the interplay between dynamic arrest and phase separation in depletion-driven colloidal mixtures. Contrary to the case of hard core plus short-range effective attraction, physical gelation without competition with the fluid-phase separation can occur in such mixtures. This behavior due to the oscillations in the depletion potential should concern all simple mixtures with a nonideal depletant, justifying further studies of their dynamic properties.