使用负载型金属纳米颗粒实现硫醇与芳基碘化物的微波高效S-芳基化反应。
Microwave efficient S-arylation of thiols with aryl iodides using supported metal nanoparticles.
作者信息
Gonzalez-Arellano Camino, Luque Rafael, Macquarrie Duncan J
机构信息
Green Chemistry Centre of Excellence, The University of York, Heslington, York, UK.
出版信息
Chem Commun (Camb). 2009 Mar 21(11):1410-2. doi: 10.1039/b818767c. Epub 2009 Jan 22.
DOI:10.1039/b818767c
PMID:19259604
Abstract
An efficient and green microwave-assisted heterogeneous S-arylation protocol, reported for the first time, provided excellent coupling conversions and selectivities in minutes of reaction using Fe (homocoupling) and Cu (cross-coupling) supported metal nanoparticles.
摘要
首次报道的一种高效绿色微波辅助多相S-芳基化方法，使用负载铁（均偶联）和铜（交叉偶联）的金属纳米颗粒，在几分钟的反应时间内即可实现优异的偶联转化率和选择性。
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