通过双还原α-二亚胺稳定的镁-镁键：[K(THF)₃]₂[LMg-MgL]（L = [(2,6-(异丙基)₂C₆H₃)NC(甲基)]₂(2⁻)）的合成与结构

Magnesium-magnesium bond stabilized by a doubly reduced alpha-diimine: synthesis and structure of [K(THF)3]2[LMg-MgL] (L = [(2,6-(i)Pr2C6H3)NC(Me)]2(2-)).

作者信息

Liu Yanyan, Li Shaoguang, Yang Xiao-Juan, Yang Peiju, Wu Biao

机构信息

State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.

出版信息

J Am Chem Soc. 2009 Apr 1;131(12):4210-1. doi: 10.1021/ja900568c.

DOI:10.1021/ja900568c

PMID:19271703

Abstract

A new Mg-Mg-bonded compound stabilized by a doubly reduced alpha-diimine ligand, K(THF)(3)[LMg-MgL] (L = (2,6-(i)Pr(2)C(6)H(3))NC(Me)(2-)), has been synthesized and characterized by single-crystal X-ray diffraction and density functional theory analysis. The Mg-Mg bond length is 2.9370(18) A.

摘要

一种由双还原α-二亚胺配体稳定的新型镁-镁键合化合物[K(THF)₃]₂[LMg-MgL]（L = [(2,6-(异丙基)₂C₆H₃)NC(甲基)]₂(2-)）已通过单晶X射线衍射和密度泛函理论分析进行了合成和表征。镁-镁键长为2.9370(18) Å。