• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

1,4-Bis(4-bromo-2,6-diisopropyl-phen-yl)-1,4-diaza-buta-1,3-diene.

作者信息

Guzei Ilia A, Hill Nicholas J, Van Hout Matthew R

机构信息

Department of Chemistry, University of Wisconsin-Madison, 1101 University Ave, Madison, WI 53706, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):o40-1. doi: 10.1107/S1600536809050843.

DOI:10.1107/S1600536809050843
PMID:21580146
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980129/
Abstract

The molecule of the title compound, C(26)H(34)Br(2)N(2), lies on a crystallographic inversion center and hence the two imine groups are s-trans. The dihedral angle between the central 1,4-diaza-buta-1,3-diene unit and the attached substituted phenyl ring is 88.4 (7)°. The structure features a C-H⋯N close contact. The crystal selected for this study proved to be a non-merohedral twin with a minor component of 21.8 (3)%.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12b3/2980129/84cc0ae14ab8/e-66-00o40-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12b3/2980129/84cc0ae14ab8/e-66-00o40-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12b3/2980129/84cc0ae14ab8/e-66-00o40-fig1.jpg

相似文献

1
1,4-Bis(4-bromo-2,6-diisopropyl-phen-yl)-1,4-diaza-buta-1,3-diene.
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):o40-1. doi: 10.1107/S1600536809050843.
2
4-{1-[4-(4-Bromo-phen-yl)-1,3-thia-zol-2-yl]-5-(4-fluoro-phen-yl)-4,5-dihydro-1H-pyrazol-3-yl}-5-methyl-1-(4-methyl-phen-yl)-1H-1,2,3-triazole.4-{1-[4-(4-溴苯基)-1,3-噻唑-2-基]-5-(4-氟苯基)-4,5-二氢-1H-吡唑-3-基}-5-甲基-1-(4-甲基苯基)-1H-1,2,3-三唑
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1956-7. doi: 10.1107/S1600536812024257. Epub 2012 May 31.
3
3,5-Bis(4-bromo-phen-yl)-1-phenyl-4,5-dihydro-1H-pyrazole.
Acta Crystallogr Sect E Struct Rep Online. 2010 May 8;66(Pt 6):o1279-80. doi: 10.1107/S1600536810015795.
4
11-[(E)-4-Bromo-benzyl-idene]-8-(4-bromo-phen-yl)-14-hy-droxy-3,13-diaza-hepta-cyclo-[13.7.1.1.0.0.0.0]tetra-cosa-1(22),15,17,19(23),20-pentaen-10-one.11 - [(E) - 4 - 溴 - 亚苄基] - 8 - (4 - 溴 - 苯基) - 14 - 羟基 - 3,13 - 二氮杂 - 七环 - [13.7.1.1.0.0.0.0]二十四 - 1(22),15,17,19(23),20 - 五烯 - 10 - 酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):o2926-7. doi: 10.1107/S1600536810042091.
5
2,3-Dibromo-3-(2-bromo-phen-yl)-1-(3-phenyl-sydnon-4-yl)propan-1-one.2,3-二溴-3-(2-溴苯基)-1-(3-苯基-4-亚胺基异恶唑啉-5-酮基)丙烷-1-酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 6;66(Pt 12):o3094. doi: 10.1107/S1600536810044776.
6
(Z)-4-Bromo-N-{(Z)-3-[(4-bromo-2,6-diisopropyl-phen-yl)imino]-butan-2-yl-idene}-2,6-diisopropyl-aniline.（Z）-4-溴-N-{（Z）-3-[(4-溴-2,6-二异丙基苯基)亚氨基]-丁-2-亚基}-2,6-二异丙基苯胺
Acta Crystallogr Sect E Struct Rep Online. 2013 Feb 1;69(Pt 2):o216. doi: 10.1107/S160053681205194X. Epub 2013 Jan 9.
7
2-(4-Bromo-phen-yl)-N-[3-(1H-imidazol-1-yl)prop-yl]quinazolin-4-amine.2-（4-溴苯基）-N-[3-（1H-咪唑-1-基）丙基]喹唑啉-4-胺
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2249. doi: 10.1107/S1600536812028115. Epub 2012 Jun 30.
8
(2E)-3-(3-Bromo-phen-yl)-1-(4-chloro-phen-yl)prop-2-en-1-one: a non-merohedral twin.（2E）-3-（3-溴苯基）-1-（4-氯苯基）丙-2-烯-1-酮：一种非等轴孪晶。
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):o1915. doi: 10.1107/S1600536809027615.
9
(E)-3-(4-Bromo-phen-yl)-3-[3-(4-bromo-phen-yl)-1H-pyrazol-1-yl]prop-2-enal.（E）-3-（4-溴苯基）-3-[3-（4-溴苯基）-1H-吡唑-1-基]丙-2-烯醛
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):o279. doi: 10.1107/S1600536809054749.
10
4-[2,3-Dibromo-3-(4-bromo-phen-yl)propano-yl]-2-phenyl-1,2,3-oxadiazol-2-ium-5-olate.4-[2,3-二溴-3-(4-溴苯基)丙酰基]-2-苯基-1,2,3-恶二唑-2-鎓-5-醇盐
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):o2818-9. doi: 10.1107/S1600536810040493.

引用本文的文献

1
2-(3-Bromo-4-meth-oxy-phen-yl)acetic acid.2-（3-溴-4-甲氧基苯基）乙酸
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 5;66(Pt 7):o1555-6. doi: 10.1107/S1600536810020143.

本文引用的文献

1
Magnesium-magnesium bond stabilized by a doubly reduced alpha-diimine: synthesis and structure of [K(THF)3]2[LMg-MgL] (L = [(2,6-(i)Pr2C6H3)NC(Me)]2(2-)).通过双还原α-二亚胺稳定的镁-镁键：[K(THF)₃]₂[LMg-MgL]（L = [(2,6-(异丙基)₂C₆H₃)NC(甲基)]₂(2⁻)）的合成与结构
J Am Chem Soc. 2009 Apr 1;131(12):4210-1. doi: 10.1021/ja900568c.
2
Dicationic sulfur analogues of N-heterocyclic silylenes and phosphenium cations.
Angew Chem Int Ed Engl. 2009;48(12):2210-3. doi: 10.1002/anie.200805198.
3
Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements.双（亚氨基）苊（BIAN）配体与s-和p-族元素配位化学的最新进展。
Dalton Trans. 2009 Jan 14(2):240-53. doi: 10.1039/b815079f. Epub 2008 Nov 12.
4
Chemistry of boryllithium: synthesis, structure, and reactivity.硼锂化合物的化学：合成、结构及反应活性
J Am Chem Soc. 2008 Nov 26;130(47):16069-79. doi: 10.1021/ja8057919.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
6
The Cambridge Structural Database: a quarter of a million crystal structures and rising.剑桥结构数据库：拥有二十五万个晶体结构且数量不断增加。
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8. doi: 10.1107/s0108768102003890. Epub 2002 May 29.
7
Late-metal catalysts for ethylene homo- and copolymerization.用于乙烯均聚和共聚的后过渡金属催化剂。
Chem Rev. 2000 Apr 12;100(4):1169-204. doi: 10.1021/cr9804644.