通过芳香脲传递立体化学：1,9和1,15远程立体控制。
Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol.
作者信息
Clayden Jonathan, Pickworth Mark, Jones Lyn H
机构信息
School of Chemistry, University of Manchester, Oxford Road, Manchester, UK M13 9PL.
出版信息
Chem Commun (Camb). 2009 Feb 7(5):547-9. doi: 10.1039/b817527f. Epub 2008 Nov 26.
DOI:10.1039/b817527f
PMID:19283286
Abstract
The well-defined conformation of an N,N'-diarylurea allows a chiral sulfinyl substituent to influence diastereoselectivity in the formation of new stereogenic centres up to 14 bond lengths away.
摘要
N,N'-二芳基脲的明确构象使手性亚磺酰基取代基能够影响在距离达14个键长的新立体中心形成过程中的非对映选择性。
Zotero 插件